Efficient Catalytic C-H Activation of Alkanes: Regioselective Carbonylation of the Terminal Methyl Group of n-Pentane by RhCl(CO)(PMe3)2

DOI: 10.1039/c39870000758

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 758 - 759 (1987)

Update date:2022-08-10

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Authors:

Sakakura, Toshiyasu

Tanaka, Masato

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Article abstract of DOI:10.1039/c39870000758

The terminal methyl group of n-pentane was regioselectively carbonylated to give n-hexanal under mild conditions (1 atm pressure of CO, room temperature) by photocatalysis in the presence of RhCl(CO)(PMe3)2.

Full text of DOI:10.1039/c39870000758

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