SYNTHESIS AND CYTOCHROME P-450-LIKE REACTIVITY OF POLYPEPTIDE-BOUND PORPHINATOIRON(III)

Article abstract of DOI:10.1016/S0040-4039(01)80886-8

Polypeptide-bound porphinatoiron(III) was synthesized.This polymer could catalyze the hydroxylation of aniline with H2O2 more effectively, and catalyze the monooxygenase-type oxidation of olefins more selectively in the porphinatoiron (III)-O2-NaBH4-Me4NOH system than non-bound porphinatoiron.