The free radical chemistry of acyl tellurides: Mechanistic studies and synthetic applications

DOI: 10.1016/0040-4039(93)85002-E

Source and publish data:

Tetrahedron Letters p. 1545 - 1548 (1993)

Update date:2022-08-16

Topics:

Authors:

Chen Chen

Crich Crich

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Article abstract of DOI:10.1016/0040-4039(93)85002-E

Photolysis of acyl aryl tellurides in the presence of thiophenol results in the clean formation of aldehydes indicating homolytic cleavage of the acyl-Te bond and the involvement of acyl radicals. Further cyclization reactions of unsaturated acyltellurides are reported together with some chemistry of the cyclization products.

Full text of DOI:10.1016/0040-4039(93)85002-E

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