Mechanistic Studies of Alkene Epoxidation Catalyzed by Nickel(II) Cyclam Comlexes. 18O Labeling and Substituent Effects

DOI: 10.1021/ja00226a029

Source and publish data:

Journal of the American Chemical Society p. 6124 - 6129 (1988)

Update date:2022-08-11

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Authors:

Kinneary, Joanne F.

Albert, Jeffrey S.

Burrows, Cynthia J.

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Article abstract of DOI:10.1021/ja00226a029

The oxidations of cyclohexene and various aryl-substituted alkenes are catalyzed by the cyclam (1,4,8,11-tetraazacyclotetradecane) complex of Ni(NO3)2 with iodosylbenzene as terminal oxidant.Epoxides are the major products; however, small amounts of ring-

Full text of DOI:10.1021/ja00226a029

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