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A Novel cis-Dioxoruthenium(VI) Complex of N,N',N"-Trimethyl-1,4,7-triazacyclononane (Me3tacn) for Organic Oxidation

DOI: 10.1039/c39940001063

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1063 - 1064 (1994)

Update date:2022-08-29

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Authors:

Cheng, Wing-ChiCheng, Wing-Chi

Yu, Wing-YiuYu, Wing-Yiu

Cheung, Kung-KaiCheung, Kung-Kai

Che, Chi-MingChe, Chi-Ming

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Article abstract of DOI:10.1039/c39940001063

The X-ray structure of + shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Angstroem and 118.3(4) deg respectively, this RuVI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and ButOOH.

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