A cis-Dioxoruthenium(VI) Complex as Active oxidant of Chloride and Organic Substrates; Preparation, Characterization, and Reactivity of cis-VI(6,6'-Cl2bpy)2O2>2+ (6,6'-Cl2bpy = 6,6'-dichloro-2,2'-bipyriridine)

Article abstract of DOI:10.1039/c39870001376

Oxidation of cis-II(6,6'-Cl2bpy)2(OH2)2>²⁺ with Ce^IV gave cis-VI(6,6'-Cl2bpy)2O2>²⁺, isolated as the diamagnetic ClO4^- salt, which rapidly oxidizes Cl^- (to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and cyclohexane to cyclohexanone)

Full text of DOI:10.1039/c39870001376

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