A cis-Dioxoruthenium(VI) Complex as Active oxidant of Chloride and Organic Substrates; Preparation, Characterization, and Reactivity of cis-VI(6,6'-Cl2bpy)2O2>2+ (6,6'-Cl2bpy = 6,6'-dichloro-2,2'-bipyriridine)

DOI: 10.1039/c39870001376

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1376 - 1377 (1987)

Update date:2022-08-24

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Authors:

Che, Chi-Ming

Leung, Wai-Ho

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Article abstract of DOI:10.1039/c39870001376

Oxidation of cis-II(6,6'-Cl2bpy)2(OH2)2>²⁺ with Ce^IV gave cis-VI(6,6'-Cl2bpy)2O2>²⁺, isolated as the diamagnetic ClO4^- salt, which rapidly oxidizes Cl^- (to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and cyclohexane to cyclohexanone)

Full text of DOI:10.1039/c39870001376

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