Advanced Synthesis and Catalysis p. 1975 - 1981 (2016)
Update date:2022-08-30
Topics:
Wang, Hai-Bin
Huang, Jing-Mei
An electrochemical method for the decarboxylative coupling of α-keto acids with ortho-phenylenediamines was developed. The reaction proceeded smoothly in aqueous solution under air and metal catalyst-free conditions to afford 2-substituted benzimidazoles in good yields. Benzothiazoles could also be synthesized by this protocol. (Figure presented.) .
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