Synthesis of thiols via palladium catalyzed methanolysis of thioacetates with borohydride exchange resin

Article abstract of DOI:10.1080/00397919508011812

Various thiols are prepared quantitatively from the corresponding thioacetates via Pd catalyzed methanolysis with borohydride exchange resin under a mild and neutral conditions. One-pot synthesis of thiols from alkyl halides through the formation of alkyl thioacetates using thioacetate exchange resin followed by methanolysis is also described.

Full text of DOI:10.1080/00397919508011812

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Synthetic Communications: An
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Organic Chemistry
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Synthesis of Thiols via
Palladium Catalyzed
Methanolysis of Thioacetates
with Borohydride Exchange
Resin
Jaesung Choi a & Nung Min Yoon a
a Department of Chemistry, Sogang University, Seoul,
121-742, Korea
Published online: 23 Sep 2006.
To cite this article: Jaesung Choi & Nung Min Yoon (1995): Synthesis of Thiols via
Palladium Catalyzed Methanolysis of Thioacetates with Borohydride Exchange Resin,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 25:17, 2655-2663
To link to this article: http://dx.doi.org/10.1080/00397919508011812
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