FLUORIDE-INDUCED 1,2-ELIMINATION OF O-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONS

DOI: 10.1246/cl.1983.1211

Source and publish data:

Chemistry Letters p. 1211 - 1214 (1983)

Update date:2022-08-11

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Authors:

Himeshima, Yoshio

Sonoda, Takaaki

Kobayashi, Hiroshi

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Article abstract of DOI:10.1246/cl.1983.1211

Fluoride-induced 1,2-elimination of o-trimethylsilylphenyl triflate provided a convenient route to benzyne under mild conditions where detriflation from an intermediary aryl anion appeared to occur in preference to protonation even in the presence of alcohols.

Full text of DOI:10.1246/cl.1983.1211

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