FLUORIDE-INDUCED 1,2-ELIMINATION OF O-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONS

DOI: 10.1246/cl.1983.1211

Source and publish data:

Chemistry Letters p. 1211 - 1214 (1983)

Update date:2022-08-11

Topics:

Authors:

Himeshima, Yoshio

Sonoda, Takaaki

Kobayashi, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1983.1211

Fluoride-induced 1,2-elimination of o-trimethylsilylphenyl triflate provided a convenient route to benzyne under mild conditions where detriflation from an intermediary aryl anion appeared to occur in preference to protonation even in the presence of alcohols.

Full text of DOI:10.1246/cl.1983.1211

Products guided by the article

Product name:Anisole

Cas No:100-66-3

R&D Labs maybe for 100-66-3

xujianqiang

Contact:86-21-57725962

Address:shanghai
Chiral Quest (Suzhou) Company Ltd

website:http://www.chiralquest.com

Contact:+86-0512-62956066

Address:B1/9, 218 Xinghu Street, Suzhou Industrial Park
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China

Relevant to this article

A Novel Synthesis of Selenium-Containing Heterocyclic Compounds. Carbonylation of Ortho-Substituted Anilines with Carbon Monoxide in the Presence of Selenium

Doi:10.1021/jo00384a045
(1987)
Synthesis of the Methanesulfonates of α-(4-Chlorophenyl)-α-[1-(2-chlorophenyl)ethenyl]-1H-1,2,4-triazole- 1-ethanol and α-[1-(2-Chlorophenyl)ethenyl]-α-(2,4-difluorophenyl)- 1H-1,2,4-triazole-1-ethanol, Aloha Styryl Carbinol Antifungal Agents

Doi:10.1002/jhet.5570350144
(1998)
Guanidinium-based derivatives: Searching for new kinase inhibitors

Doi:10.1016/j.ejmech.2014.05.025
(2014)
NiAl and CoAl materials derived from takovite-like LDHs and related structures as efficient chemoselective hydrogenation catalysts

Doi:10.1039/c3cy00611e
(2014)
Effect of La₂O₃-dopping on the Al₂O ₃ supported cobalt catalyst for Fischer-Tropsch synthesis

Doi:10.1016/j.molcata.2010.06.025
(2010)
Regioselectivity in Nucleophilic Ring Opening of 2-Methylaziridines. Lag of Bond Making as Model for the Abnormal Opening

Doi:10.1002/prac.19933350105
(1993)

Article Doi