Bulletin of the Chemical Society of Japan p. 3176 - 3178 (1991)
Update date:2022-08-11
Topics:
Yoshimura, Toshiaki
Tsukurimichi, Eiichi
Sugiyama, Yasuhisa
Kita, Hiroshi
Shimasaki, Choichiro
Hasegawa, Kiyoshi
The reaction of S,S-diphenyl-S-methoxythiazyne with various thiols gave methyl sulfides.Kinetic investigations support a mechanism involving an initial protonation of the thiazyne nitrogen with thiol followed by a nucleophilic attack of thiolate anion on the methyl group.
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