Synthetic Communications p. 683 - 690 (2007)
Update date:2022-08-11
Topics:
Zhang, Zhiqiang
Hu, Zhizhi
Yu, Zhixiao
Chi, Haijun
Lei, Peng
Wang, Yue
He, Ren
The synthesis of unsymmetrical biaryls with a methylthio group is achieved using the air-stable palladium-phosphinous acid complexes, [(t-Bu)2P(OH)]2 PdCl2 (POPd), as the catalyst. A great variety of substituted bromobenzenes having electron-withdrawing and electron-donating functional groups in para and meta positions have been successfully coupled with 3-methylthiophenylboronic acid. Copyright Taylor & Francis Group, LLC.
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