Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 735 - 746 (1982)
Update date:2022-08-11
Topics:
Naito, Shuichi
Tamaru, Kenzi
It is demonstrated that the reduction of nitric oxide by dinitro-(alkyldiamine) Co(III) complexes proceeds through the dissociation of the amine group of the alkyldiamine ligand, followed by the formation of mononitrosyl and dinitrosyl intermediate complexes from which N2 and N2O are produced, respectively.In aqueous solution, the coordination of NO and NH3 to the catalytically active intermediate complex is the rate-determining step, which shifts to the reaction of coordinated nitric oxide with ammonia in DMF solution.The stabilities of these intermediate complexes depend on the structure of the alkyldiamine ligands, which cause different selectivities for N2 and N2O formation.
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(1990)
