Journal of the Chemical Society. Chemical communications p. 310 - 311 (1980)
Update date:2022-08-15
Topics:
Kresge, A. J.
Tang, Y. C.
Awwal, A.
Kinetic hydrogen isotope effects on the decomposition of nitramide catalysed by a series of phosphonate anions and the 2,4,6-trichlorophenoxide ion were found to be small (kH/kD ca. 2 - 3) with no sign of a maximum value of pKa (catalyst conjugate acid) ca. 6, in disagreement with a previously reported claim but consistent with the expected pKa of the reactive form of the substrate.
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