Journal of Organometallic Chemistry p. 147 - 152 (1996)
Update date:2022-08-23
Topics:
Paetzold
Roewer
Herzog
Bu3SnH is an effective reagent for partial conversion of Si-Cl into Si-H groups. The presented hydrogenation mechanism postulates the coordination of the catalyst (Lewis bases) or the solvent to silicon, giving an intermediate with higher coordinated silicon atom in the first step, followed by the attack of tributyltin hydride by a single electron transfer. This mechanism implies that the intermediate having a hypervalent silicon atom reacts more rapidly than the starting tetracoordinated silane.
ZHEJIANG CHEMICAL INDUSTRY INSTITUTE TECHNOLOGY CO.,LTD(expird)
Contact:86-575-82730298
Address:shangyu
Anhui Asahikasei Chemical Co., Ltd
Contact:86-551-4259770
Address:No. 88 Linquan Road Hefei Anhui China
JiangXi Keyuan Biopharma Co., LTD.
Contact:+86-563-6833666
Address:Guangde Fine Chemical Zone, Anhui Province, China
Contact:0086-22-23410962
Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
website:http://www.mingchem.com/en/index
Contact:0519-85170101-802
Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Doi:10.1039/c9ta04073k
(2019)Doi:10.1055/s-2001-10794
(2001)Doi:10.1016/S0040-4039(01)80527-X
(1989)Doi:10.1149/1.1391999
(1999)Doi:10.1002/ardp.19763091102
(1976)Doi:10.1021/ja01164a056
(1950)
