Temperature dependence of the rate constants for the H + Br2 and D + Br2 reactions

Article abstract of DOI:10.1063/1.460574

The rate constants for the reactions of H + Br2 and D + Br2 were measured by employing a pulse radiolysis-resonance absorption technique.The rate constants could be expressed by the following Arrhenius equations between 214 and 295 K: k(H + Br2) = 6.7 x 10^-10 exp( - 680/T), k(D + Br2) = 6.0 x 10^-10 exp( - 720/T), in units of cm³ s^-1.Sudden transition state theoretical calculations were performed on the basis of modified LEPS surfaces.The calculated results were compared with the experimental ones.

Full text of DOI:10.1063/1.460574

Temperature dependence of the rate constants for the H+Br2 and D+Br2 reactions
Youichi Wada, Toshiyuki Takayanagi, Hironobu Umemoto, Shigeru Tsunashima, and Shin Sato
Citation: The Journal of Chemical Physics 94, 4896 (1991); doi: 10.1063/1.460574
View online: http://dx.doi.org/10.1063/1.460574
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/94/7?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.174.255.116 On: Sat, 29 Nov 2014 11:16:44
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.174.255.116 On: Sat, 29 Nov 2014 11:16:44
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.174.255.116 On: Sat, 29 Nov 2014 11:16:44
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.174.255.116 On: Sat, 29 Nov 2014 11:16:44
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