Journal of Organic Chemistry p. 7516 - 7523 (1993)
Update date:2022-08-17
Topics:
House
Holt
VanDerveer
A synthesis has been developed for 2,7-dimethyl-1,8-di-o-tolylanthracene 4. The cis 4a and trans 4b isomers of this hydrocarbon can be separated and are stable to interconversion at temperatures below 200 °C. The two enantiomers of the trans isomer 4b have chiral cavities and are expected to be useful precursors for chiral reagents or chiral catalysts.
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