Tetrahedron Letters p. 2735 - 2738 (1985)
Update date:2022-08-10
Topics:
Piers, Edward
Moss, Neil
The key step of a new approach to the total synthesis of the structurally and physiologically interesting sesquiterpenoid (+/-)-quadrone (1) involves thermal (Cope) rearrangement of the higly functionalized divynilcyclopropane derivative 8.The product 9 of this process is converted into 19, thus completing a formal total synthesis of (+/-)-1.
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