Journal of the Chemical Society. Perkin transactions I p. 78 - 81 (1981)
Update date:2022-08-31
Topics:
Jones, Gurnos
Sliskovic, D. Robert
Foster, Beverley
Rogers, John
Smith, Anthony K.
et al.
On treatment with chlorine, bromine, or mercuric acetate triazolo<1,5-a>pyridine (1) gives dichloromethyl-, dibromomethyl-, and alkoxy(alkoxymercurio)methyl-pyridines (3), (4), (5), and (8) with loss of nitrogen.Nitration gives 3-nitrotriazolopyridine (9), which on reduction gives 3-(2-pyridyl)imidazo<1,5-a>pyridine (11).The mechanism of formation of these compounds is discussed.
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