Organic Letters p. 6316 - 6319 (2017)
Update date:2022-08-17
Topics:
Kang, Byung Chul
Shin, Sung Ho
Yun, Jaesook
Ryu, Do Hyun
A highly enantioselective hydrosilylation of ketones was developed for the synthesis of a variety of chiral secondary alcohols. In the presence of a chiral oxazaborolidinium ion (COBI) catalyst, the reaction proceeded with good yields (up to 99%) with excellent enantioselectivities (up to 99% ee).
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