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50 MHz)
d 21.5, 126.6, 128.3 (2C), 128.4 (2C), 129.0 (2C), 129.1 (2C),
Stanforth, S. P. Tetrahedron 1998, 54, 263; (c) Suzuki, A. J. Organomet. Chem.
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348, 609.
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references therein.
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136.5, 137.9, 140.6.
4.3.23. 4,40-Dimethoxybiphenyl (5w)
Pale yellow solid. Mp 178–180 ꢀC (lit.13 178–180 ꢀC). 1H NMR
(CDCl3, 200 MHz)
d
3.84 (s, 6H), 6.96 (d, J¼8.8 Hz, 4H), 7.48 (d,
J¼8.8 Hz, 4H); 13C NMR (CDCl3, 50 MHz)
d 55.5 (2C), 114.4 (4C),
127.3 (4C), 133.0 (2C), 158.0 (2C).
4.3.24. 4-Methoxy-40-methylbiphenyl (5x)
White solid. Mp 113–114 ꢀC (lit.13 113–114 ꢀC). 1H NMR (CDCl3,
200 MHz)
d
2.38 (s, 3H), 3.84 (s, 3H), 6.95 (d, J¼8.8 Hz, 2H), 7.21 (d,
J¼8.0 Hz, 2H), 7.44 (d, J¼8.0 Hz, 2H), 7.50 (d, J¼8.8 Hz, 2H); 13C NMR
(CDCl3, 50 MHz) d 21.5, 55.5, 113.8 (2C), 126.2 (2C), 127.6 (2C), 129.0
(2C), 133.3, 135.9, 137.5, 158.3.
4.3.25. 4-Fluoro-40-methoxybiphenyl (5y)
White solid. Mp 88–90 ꢀC (lit.28 87.3–87.8 ꢀC). 1H NMR (CDCl3,
200 MHz)
d
3.85 (s, 3H), 6.95–6.99 (m, 2H), 7.08–7.12 (m, 2H), 7.45–
55.5, 113.9 (2C), 115.2 (2C),
7.51 (m, 4H); 13C NMR (CDCl3, 50 MHz)
d
127.6 (2C), 127.8, 132.3 (2C), 134.5, 158.7, 162.4 (q, JC–F¼243.2 Hz).
4.3.26. 4-Methoxy-20-methylbiphenyl (5z)
Colorless oil.27 1H NMR (CDCl3, 200 MHz)
d 2.27 (s, 3H), 3.84 (s,
3H), 6.94 (d, J¼8.6 Hz, 2H), 7.21–7.27 (m, 6H); 13C NMR (CDCl3,
50 MHz) d 20.5, 55.3, 113.5 (2C), 125.7, 126.9, 129.8, 130.1, 130.2 (2C),
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134.4, 135.4, 141.5, 158.5.
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4.3.27. 4-Hydroxy-20-methylbiphenyl (5aa)
´
´
´
2287; (f) Gordillo, A.; de Jesus, E.; Lopez-Mardomingo, C. Org. Lett. 2006, 8,
Pale yellow oil.29 1H NMR (CDCl3, 200 MHz)
d 2.28 (s, 3H), 4.86
´
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50 MHz)
154.4.
d 20.5, 114.9, 126.9, 129.8, 130.2, 130.4, 134.5, 135.4, 141.5,
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This research was financially supported by the National Science
Council of Taiwan (NSC96-2113-M-027-003-MY2).
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