Kinetic study of the reaction of atomic chlorine with hydrogen bromide

Article abstract of DOI:10.1063/1.446366

The reaction Cl + HBr --> HCl + Br was studied by a competitive method using the reaction Cl + C2H6 --> HCl + C2H5 as a reference reaction.Experiments to determine ratios of rate constants k_Cl+HBr/k_Cl+C2H6 in the temperature range 222-504 K were carried out in a fast flow system with mass spectrometric analysis of the reaction mixture.The results fit the Arrhenius expression: k_Cl+HBr/k_Cl+C2H6 = (0.53+/-0.03)exp<-(321+/-16)/T>.A comparison is made with values calculated from reported results for the individual rate constants k_Cl+HBr and k_Cl+C2H6.

Full text of DOI:10.1063/1.446366

Kinetic study of the reaction of atomic chlorine with hydrogen bromide
Rachamim Rubin and Avigdor Persky
Citation: The Journal of Chemical Physics 79, 4310 (1983); doi: 10.1063/1.446366
View online: http://dx.doi.org/10.1063/1.446366
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/79/9?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
29.22.67.107 On: Mon, 24 Nov 2014 08:11:23
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
29.22.67.107 On: Mon, 24 Nov 2014 08:11:23
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
29.22.67.107 On: Mon, 24 Nov 2014 08:11:23
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
29.22.67.107 On: Mon, 24 Nov 2014 08:11:23
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
29.22.67.107 On: Mon, 24 Nov 2014 08:11:23
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