Chemistry Letters p. 357 - 360 (1986)
Update date:2022-08-16
Topics:
Mine, Norioki
Fujiwara, Yuzo
Taniguchi, Hiroshi
The usual Friedel-Crafts catalysts cannot be re-used after aqueous work-up.An alternative catalyst, based on rare earths has been found, which serves as an efficient Friedel-Crafts catalyst for alkylation of arenes by alkyl halides, and can be re-used after the reaction.Typical examples are shown in the reaction of benzene with benzyl halides using all of the rare earth trichlorides as catalyst, except PmCl3.
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