Chemistry Letters p. 1131 - 1132 (1985)
Update date:2022-08-11
Topics:
Nemoto, Hideo
Kimura, Toshihiko
Kurobe, Hiroshi
Fukumoto, Keiichiro
Kametani, Tetsuji
A stereoselective synthesis of 1 α-hydroxy-vitamin D3 was achieved through the solvolysis of the 3,5-cyclovitamin D3 which was prepared from (-)-(3S,5R) -2-methylene-3-methoxymethyloxybicyclo<3.1.0>hexanecarboxaldehyde and the des-AB-8-bromomethylenecholestane.
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Doi:10.1021/ja01627a058
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