Correlation of X-Ray Crystal Structures of Chiral Bisphosphine-Rhodium Catalysts and the Absolute Configuration of the Products Resulted by Their Asymmetric Hydrogenations

DOI: 10.1016/S0957-4166(00)86111-X

Source and publish data:

Tetrahedron Asymmetry p. 597 - 600 (1991)

Update date:2022-08-16

Topics:

Authors:

Sakuraba, S.

Morimoto, T.

Achiwa, K.

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Article abstract of DOI:10.1016/S0957-4166(00)86111-X

The chiral positioning array (P/M-chirality) of four phenyl rings in the rhodium-chiral bisphosphine catalyst has been revealed to play an important tole in determining the absolute configuration of the asymmetric hydrogenation product.

Full text of DOI:10.1016/S0957-4166(00)86111-X

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