Asymmetric Hydrogenation with Chiral Aminophosphine-Rhodium Complexes and Chiral Recognition by Bisphosphine-Rhodium Complexes in the Asymmetric Hydrogenation of Olefins through the Chiral Helical Conformation of Phenyl Groups on the Phosphorus Atom

Article abstract of DOI:10.1246/bcsj.53.2016

The asymmetric hydrogenation of α-acylaminocinnamic acids with the rhodium complex of (1R,2R)-1,2-bis(N-diphenylphosphino-N-methylamino)cyclohexane has been reported to give preferentially (S)-amino acids.On the contrary, it has been found that the enanti