Conversion of Aliphatic and Alicyclic Carboxylic Acids into nor-Hydroperoxides, nor-Alcohols, and nor-Oxo Derivatives using Radical Chemistry

DOI: 10.1039/c39840000242

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 242 - 244 (1984)

Update date:2022-08-25

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Authors:

Barton, Derek H. R.

Crich, David

Motherwell, William B.

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Article abstract of DOI:10.1039/c39840000242

Radicals generated from esters of N-hydroxypyridine-2-thione react smoothly with oxygen in the presence of t-butyl thiol to furnish nor-hydroperoxides, from which the corresponding alcohols and carbonyl derivatives can be readily obtained.

Full text of DOI:10.1039/c39840000242

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