10.1002/anie.201800884
Angewandte Chemie International Edition
COMMUNICATION
[8]
[9]
Y. Bai, Y. Dou, L.-H. Xie, W. Rutledge, J.-R. Li, H.-C. Zhou, Chem. Soc.
Rev. 2016, 45, 2327.
C. Serre, F. Millange, C. Thouvenot, M. Noguès, G. Marsolier, D. Louër,
G. Férey, J. Am. Chem. Soc. 2002, 124, 13519.
[10] G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S.
Surblé, I. Margiolaki, Science 2005, 309, 2040.
[11] T. Devic, C. Serre, Chem. Soc. Rev. 2014, 43, 6097.
[12] K. Leus, T. Bogaerts, J. De Decker, H. Depauw, K. Hendrickx, H.
Vrielinck, V. Van Speybroeck, P. Van Der Voort, Micropor. Mesopor.
Mater. 2016, 226, 110.
[13] I. Carson, M. R. Healy, E. D. Doidge, J. B. Love, C. A. Morrison, P. A.
Tasker, Coord. Chem. Rev. 2017, 335, 150.
Figure 4. Structural and functional variability of phosphinic acid based linkers
(left) and MOF prepared using phenylene-1,4-bis(phenylphosphinic acid)
(right).
[14] J.-L. Du, S. J. Rettig, R. C. Thompson, J. Trotter, Can. J. Chem. 1991,
69, 277.
[15] E. Oleshkevich, C. Viꢀas, I. Romero, D. Choquesillo-Lazarte, M.
Haukka, F. Teixidor, Inorg. Chem. 2017, 56, 5502.
[16] W. Yang, H. Wang, W.-G. Tian, J. Li, Z.-M. Sun, Eur. J. Inorg. Chem.
2014, 31, 5378.
In summary, the structural diversity of possible di-, tri- and tetra-
valent phosphinic acid based linkers, coupled with the enhanced
hydrothermal stability of the resulting MOFs, gives promise for
many phosphinic acid based MOF structures with large potential
for applications in various fields of research and industry.
The majority of MOF structures published in recent years are
solved from micro/nanocrystaline powders and often the
structural solution is possible only with the use of prior
knowledge of the structure of the inorganic nodes and organic
linkers. Here, we demonstrate the potential and suitability of
electron diffraction tomography, used with dynamical refinement,
for the structure determination of MOFs. In addition, the
possibility to localize hydrogen atoms in the MOF structures
implies distinguishing between coordinated H2O, -OH, and =O at
the inorganic nodes. Because many of the MOF applications
take advantage of the open metal sites at the inorganic nodes,
this information regarding the positions of hydrogen atoms is
crucial to the rationalization of the structure-properties
relationship.
[17] F. Costantino, A. Ienco, S. Midollini, A. Orlandini, L. Sorace, A. Vacca,
Eur. J. Inorg. Chem. 2008, 3046.
[18] F. Cecconi, D. Dakternieks, A. Duthie, C. A. Ghilardi, P. Gili, P. A.
Lorenzo-Luis, S. Midollini, A. Orlandini, J. Solid State Chem. 2004, 177,
786.
[19] R. Shekurov, V. Miluykov, O. Kataeva, D. Krivolapov, O. Sinyashin, T.
Gerasimova, S. Katsyuba, V. Kovalenko, Y. Krupskaya, V. Kataev, B.
Büchner, I. Senkovska, S. Kaskel, Cryst. Growth Des. 2016, 16, 5084.
[20] U. Kolb, T. Gorelik, C. Kübel, M. T. Otten, D. Hubert, Ultramicroscopy
2007, 107, 507.
[21] D. Zhang, P. Oleynikov, S. Hovmöller, X. Zou, Z. Kristallogr. 2010, 225,
94.
[22] L. Zhu, D. Zhang, M. Xue, H. Li, S. Qiu CrystEngComm 2013, 15, 9356.
[23] Y. Zhu, J. Ciston, B. Zheng, X. Miao, C. Czarnik, Y. Pan, R. Sougrat, Z.
Lai, C.-E. Hsiung, K. Yao, I. Pinnau, M. Pan, Y. Han, Nat. Mater. 2017,
16, 532.
[24] M. Feyand , E. Mugnaioli , F. Vermoortele , B. Bueken , J. M. Dieterich ,
T. Reimer , U. Kolb , D. de Vos , N. Stock, Angew. Chem. Int. Ed. 2012 ,
51 , 10373; Angew. Chem. 2012, 124, 10519.
[25] R. Dai, F. Peng, P. Ji, K. Lu, C. Wang, J. Sun, W. Lin, Inorg. Chem.
2017, 56, 8128.
[26] D. Denysenko, M. Grzywa, M. Tonigold, B. Streppel, I. Krkljus, M.
Hirscher, E. Mugnaioli, U. Kolb, J. Hanss, D. Volkmer Chem. Eur. J.
2011, 17, 1837.
Acknowledgements
[27] L. Palatinus, PETS – Program for Analysis of Electron Diffraction Data
(Institute of Physics of the Czech Academy of Sciences, 2011).
[28] V. Petříček, M. Dušek, L. Palatinus, Z. Kristallogr. 2014, 229, 345–352.
[29] L. Palatinus, G. Chapuis, J. Appl. Cryst. 2007, 40, 786.
[30] L. Palatinus, C. A. Corrêa, G. Steciuk, D. Jacob, P. Roussel, P. Boullay,
M. Klementová, M. Gemmi, J. Kopeček, M. C. Domeneghetti, F.
Cámara, V. Petříček, Acta Crystallogr. B 2015, 71, 740.
[31] L. Palatinus, P. Brázda, P. Boullay, O. Perez, M. Klementová, S. Petit,
V. Eigner, M. Zaarour, S. Mintova, Science 2017, 355, 166.
[32] M. Taddei, F. Costantino, R. Vivani, Inorg. Chem. 2010, 49, 9664.
This work was financially supported by the Czech Science
Foundation (No. 16-02098S). We thank Jan Rohovec for the
measurements of ICP-OES. The crystallographic part was
supported by the project ASTRA of the Operation program
Prague Competitiveness - project CZ.2.16/3.1.00/24510.
Keywords: Coordination polymers • phosphinic acid • chemical
stability • electron diffraction • dynamical refinement
[33] Poreblazer
v3.0.2
(2017):
[1]
[2]
M. Eddaoudi M, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe and
O. M. Yaghi, Science, 2002, 295, 469.
[34] T. Düren, F. Millange, G. Férey, K. S. Walton and R. Q. Snurr, J. Phys.
Chem. C, 2007, 111, 15350.
D. J. Tranchemontagne, J. L. Mendoza-Cortés, M. O’Keeffea, O. M.
Yaghi, Chem. Soc. Rev. 2009, 38, 1257.
[35] L. Sarkisov, A. Harrison, Mol. Simul. 2011, 37, 1248.
[3]
[4]
S. Qiu, M. Xue, G. Zhu, Chem. Soc. Rev. 2014, 43, 6116.
A. H. Chughtai, N. Ahmad, H. A. Younus, A. Laypkov, F. Verpoort,
Chem. Soc. Rev. 2015, 44, 6804.
[5]
[6]
Z. Hu, B. J. Deibert, J. Li, Chem. Soc. Rev. 2014, 43, 5815.
P. Horcajada, R. Gref, T. Baati, P. K. Allan, G. Maurin, P. Couvreur, G.
Férey, R. E. Morris, C. Serre, Chem. Rev. 2012, 112, 1232.
J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S.
Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850.
[7]
This article is protected by copyright. All rights reserved.