Journal of Organic Chemistry p. 4731 - 4733 (1986)
Update date:2022-08-11
Topics:
Hwu, Jih Ru
Chua, Vincent
Schroeder, Jean E.
Barrans, Richard E.
Khoudary, Kevin P.
et al.
Extremely high selectivity was provided by calcium in liquid ammonia in the cleavage of the benzylic carbon-oxygen bond in benzyl ethers containing various other functionalities.Results of controlled experiments indicate that the selectivities offered by the Ca -> Ca+ + e- and the Ca+ -> Ca2+ + e- processes are 4.6 and 47 times greater, respectively, than that afforded by the Li -> Li+ + e- process.
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