OBSERVATIONS ON A NICKEL-CATALYZED ISOMERIZATION OF ALLYLIC LITHIUM ALKOXIDES

DOI: 10.1016/S0040-4039(00)60039-4

Source and publish data:

Tetrahedron Letters p. 6187 - 6190 (1992)

Update date:2022-08-30

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Authors:

Motherwell, William B.

Sandham, David A.

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Article abstract of DOI:10.1016/S0040-4039(00)60039-4

Use of complex (Cy3)2NiCl2 rather than ClO4 as catalyst facilitates regioselective preparation of lithium enolates via isomerization of the corresponding allylic alkoxides.The nickel catalyst also succeeds in isomerizing certain di- and trisubst

Full text of DOI:10.1016/S0040-4039(00)60039-4

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