Tetrahedron p. 10389 - 10402 (1998)
Update date:2022-08-11
Topics:
Denmark, Scott E.
Stavenger, Robert A.
Wong, Ken-Tsung
The trichlorosilyl enolates of cyclopentanone and cycloheptanone were prepared by a mercury(II)-catalyzed metathesis from their TMS enol ethers in good yield. These enolates undergo spontaneous addition to aldehydes to provide the aldol adducts syn-4, 5a-
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