Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 557 - 560 (1990)
Update date:2022-08-11
Topics:
Pletnev, S. I.
Igumnov, S. M.
Zakharova, E. V.
Makarov, K. N.
It is shown for the first time that bromination and iodination of tertiary perfluorocarbanions are reversible.The tendency of tertiary perfluoroalkyl halides to undergo dehalofluorination under the influence of weak bases depends on the structure of the perfluoroalkyl halide, and increases in going from lower to higher halides and from linear to cyclic compounds.
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