Bulletin of the Chemical Society of Japan p. 1021 - 1026 (1987)
Update date:2022-08-16
Topics:
Maruyama, Kazuhiro
Osuka, Atsuhiro
Nakagawa, Katsuhiko
Irradiation of a benzene solution of 2,3-epoxy-2,3-dihydro-2,3-dimethyl-1,4-naphthoquinone with olefins containing amide group, i.e., N-substituted acrylamides and N-allylcarboxamides predominantly gave the endo-cycloadducts.Upon further irradiation, the cycloadducts underwent photorearrangement to give spirophthalides and alkylidenephthalides.
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