CONVERSION OF ORGANIC HALIDES BY CO INTO ALDEHYDES USING ELECTROREDUCED Fe(CO)5

DOI: 10.1016/S0040-4039(00)82367-9

Source and publish data:

Tetrahedron Letters p. 6441 - 6442 (1988)

Update date:2022-08-31

Topics:

Authors:

Vanhoye, Didier

Bedioui, Fethi

Mortreux, Andre

Petit, Francis

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Article abstract of DOI:10.1016/S0040-4039(00)82367-9

Reduction of Fe(CO)5 and RX (RX = EtI ; PhCH2Br) by controlled potential electrolysis leads to the production of Fe(CO)5^-. and R^. radicals which, in CO, undergo stoechiometric carbonylation of the organic halide into aldehyde, after hydrolysis.

Full text of DOI:10.1016/S0040-4039(00)82367-9

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