Selective reduction of alkynes to Z-alkenes using hydrosilane functions immobilized on silica gel

DOI: 10.1016/S0040-4039(00)76744-X

Source and publish data:

Tetrahedron Letters p. 1507 - 1510 (1994)

Update date:2022-08-11

Topics:

Authors:

Kini, Abhay D.

Nadkarni, Durgesh V.

Fry, James L.

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Article abstract of DOI:10.1016/S0040-4039(00)76744-X

A solid reagent consisting of hydrosilane functions immobilized on the surface of silica gel was used in conjunction with acetic acid and tetrakis(triphenylphosphine)palladium(0) catalyst to effect the reduction of alkynes to Z-olefins. Simple filtration provides a convenient means for the reaction workup and isolation of products.

Full text of DOI:10.1016/S0040-4039(00)76744-X

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