Phenolic Solvent-Assisted Hydrogenolysis of trans-Stilbene

DOI: 10.1246/bcsj.59.2869

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2869 - 2872 (1986)

Update date:2022-08-16

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Authors:

Mizuki, Tatsuro

Futamura, Shigeru

Kamiya, Yoshio

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Article abstract of DOI:10.1246/bcsj.59.2869

Phenolic solvents such as phenol, 3,4-xylenol, 2-naphthol, and 5,6,7,8-tetrahydro-2-naphthol greatly promote toluene formation in the hydrogenolysis of trans-stilbene, compared with hydroaromatic hydrocarbon solvents.Toluene is afforded in the thermal decomposition of the phenolic solvent adduct to trans-stilbene, not via bibenzyl.

Full text of DOI:10.1246/bcsj.59.2869

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