A NEW REDUCTION SYSTEM: COMBINATION OF SODIUM SULFIDE (SODIUM HYDROSULFIDE) WITH PHASE TRANSFER AGENT IN A TWO PHASE MIXTURE. REDUCTIVE DEBROMINATION OF vic-DIBROMIDES TO OLEFINS

DOI: 10.1016/S0040-4039(00)88080-6

Source and publish data:

Tetrahedron Letters p. 3001 - 3004 (1983)

Update date:2022-08-17

Topics:

Authors:

Nakayama, Juzo

Machida, Haruki

Hoshino, Masamatsu

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Article abstract of DOI:10.1016/S0040-4039(00)88080-6

A wide variety of vic-dibromides are debrominated to the corresponding olefins in good to excellent yields by aqueous sodium sulfide or sodium hydrosulfide using trioctylmethylammonium chloride as the phase transfer agent in a two-phase mixture.

Full text of DOI:10.1016/S0040-4039(00)88080-6

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