Chemische Berichte p. 741 - 743 (1996)
Update date:2022-08-25
Topics:
Reetz, Manfred T.
Quaiser, Stefan A.
Merk, Claudia
The electrochemical preparation of nanostructured titanium clusters is possible by using a titanium sacrificial anode as the metal source and tetrabutylammonium bromide in THF as the electrolyte and stabilizer. Transmission electron mi-croscopy shows the presence of spherical 3.0-nm-sized particles. THF solutions of these Ti clusters induce olefin-forrning McMurry-type coupling of aldehydes and ketones. VCH Verlagsgesellschaft mbH, 1996.
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