Trichlorosilane-dimethylformamide (Cl3SiH-DMF) as an efficient reducing agent. Reduction of aldehydes and imines and reductive amination of aldehydes under mild conditions using hypervalent hydridosilicates

DOI: 10.1246/cl.1996.407

Source and publish data:

Chemistry Letters p. 407 - 408 (1996)

Update date:2022-08-17

Topics:

Authors:

Kobayashi, Shu

Yasuda, Masaru

Hachiya, Iwao

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Article abstract of DOI:10.1246/cl.1996.407

Trichlorosilane-dimethylformamide (Cl₃SiH-DMF) was found to be an effective reducing agent for reduction of aldehydes to alcohols, imines to amines, and also reductive amination of aldehydes. Hypervalent silicates are active species, which enable efficient reduction under mild conditions.

Full text of DOI:10.1246/cl.1996.407

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