Journal of the Chemical Society - Faraday Transactions p. 4291 - 4295 (1996)
Update date:2022-08-29
Topics:
Ohtani, Bunsho
Goto, Yosuke
Nishimoto, Sei-Ichi
Inui, Tomoyuki
Photoirradiation at >300 nm of platinized titanium(IV) oxide (TiO2-Pt) or cadmium(II) sulfide loaded with platinum(IV) oxide suspended in propan-2-ol has been shown to lead to transfer hydrogenation of Schiff bases [N-benzylidenebenzylamine (BdBA) and N-benzylideneaniline] to the corresponding secondary amines [dibenzylamine (DBA) and N-benzylaniline, respectively]. Dehydrogenation of propan-2-ol also occurred as a side reaction. The transfer hydrogenation required both the photoirradiation and suspended semiconductor particles, indicating that photoexcited electrons and positive holes induces the reaction. Platinization of the semiconductor particles was also necessary and TiO2-Pt prepared by impregnation followed by H2 reduction showed the highest yield of DBA from BdBA. The most efficient catalyst was prepared by reduction at an H2 flow rate of 35 cm3 min-1 and had small Pt deposits dispersed uniformly on each TiO2 particle. Addition of molecular sieve 3A to the reaction mixture improved the selectivity to DBA from BdBA by absorbing contaminant water and thereby inhibiting the hydrolysis of BdBA and subsequent formation of N-benzylpropyl-2-amine.
View MoreChongqing Yawei Fine Chemical Co.,Ltd
Contact:0086-23-62849407
Address:Ziyou village, Nanquan town, Banan district, Chongqing China
Ningbo Tide Imp. & Exp. Co., Ltd.
Contact:+86-571-8993 7933; +86-571-8993 6453
Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
website:https://www.bocsci.com/
Contact:1-631-485-4226
Address:Ramsey Road
Contact:86-510-82853889
Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
Disynthesis Chemical Technology Co. Ltd.
Contact:+86-571-88194596
Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Doi:10.1021/ol3033048
(2013)Doi:10.1039/c39800000753
(1980)Doi:10.1002/kin.21264
(2019)Doi:10.1149/1.1389342
(2001)Doi:10.1080/00958972.2013.820827
(2013)Doi:10.1021/acsmedchemlett.9b00204
(2019)
