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Photocatalytic transfer hydrogenation of Schiff bases with propan-2-ol by suspended semiconductor particles loaded with platinum deposits

DOI: 10.1039/ft9969204291

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 4291 - 4295 (1996)

Update date:2022-08-29

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Authors:

Ohtani, BunshoOhtani, Bunsho

Goto, YosukeGoto, Yosuke

Nishimoto, Sei-IchiNishimoto, Sei-Ichi

Inui, TomoyukiInui, Tomoyuki

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Article abstract of DOI:10.1039/ft9969204291

Photoirradiation at >300 nm of platinized titanium(IV) oxide (TiO2-Pt) or cadmium(II) sulfide loaded with platinum(IV) oxide suspended in propan-2-ol has been shown to lead to transfer hydrogenation of Schiff bases [N-benzylidenebenzylamine (BdBA) and N-benzylideneaniline] to the corresponding secondary amines [dibenzylamine (DBA) and N-benzylaniline, respectively]. Dehydrogenation of propan-2-ol also occurred as a side reaction. The transfer hydrogenation required both the photoirradiation and suspended semiconductor particles, indicating that photoexcited electrons and positive holes induces the reaction. Platinization of the semiconductor particles was also necessary and TiO2-Pt prepared by impregnation followed by H2 reduction showed the highest yield of DBA from BdBA. The most efficient catalyst was prepared by reduction at an H2 flow rate of 35 cm3 min-1 and had small Pt deposits dispersed uniformly on each TiO2 particle. Addition of molecular sieve 3A to the reaction mixture improved the selectivity to DBA from BdBA by absorbing contaminant water and thereby inhibiting the hydrolysis of BdBA and subsequent formation of N-benzylpropyl-2-amine.

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