Angewandte Chemie - International Edition p. 1128 - 1132 (2010)
Update date:2022-08-17
Topics:
Tagusagawa, Caio
Takagaki, Atsushi
Iguchi, Ai
Takanabe, Kazuhiro
Kondo, Junko N.
Ebitani, Kohki
Hayashi, Shigenobu
Tatsumi, Takashi
Domen, Kazunari
Pore-ing acid: Mesoporous Nb-W oxides (Nb:W = 3:7) are found to be a recyclable, highly active solid acid. They surpass ionexchange resins (Naflon NR50 and Amberlyst-15) and zeolites (H-ZSM5 and H-Beta) in Friedel-Crafts alkylation and hydrolysis reactions (see picture). The high activity is due to strong acid sites and a mesoporous structure with a high surface area and easy reactant accessibility. (Figure Presented)
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(2004)Doi:10.1039/c8ra00603b
(2018)Doi:10.1021/op900085b
(2009)Doi:10.1271/bbb.66.934
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