Tetrahedron Letters p. 87 - 90 (1982)
Update date:2022-08-17
Topics:
Uemura, Sakae
Fukuzawa, Shin-ichi
Toshimitsu, Akio
Okano, Masaya
Treatment of several cyclic olefins, β-pinene, allylbenzene and estragole with palladium(II) salt in acetic acid in the presence of t-butyl hydroperoxide and tellurium(IV) oxide afforded mainly the corresponding allylic acetates.The reaction proceeded catalytically with palladium(II) salt, t-BuOOH working as a reoxidazing agent.
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Doi:10.1021/acs.joc.6b01950
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