Bulletin of the Chemical Society of Japan p. 2031 - 2038 (1996)
Update date:2022-08-17
Topics:
Satoh, Masahiro
Hirota, Minoru
A rapid and convenient method for the evaluation of activation enthalpies and entropies of reactions in solutions was contrived. This was realized by the stepwise elevation of the temperature of a reaction system using a variable temperature apparatus of NMR spectrometer. A repetition of rapid collection of FIDs (Free Inductive Decays) at every plateau part of temperature at regular intervals allows us to determine the time-conversion curve, from which the rates at various temperatures were obtained as the first derivatives. Several examples of applications are shown.
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