Journal of Organic Chemistry p. 3888 - 3890 (1988)
Update date:2022-08-15
Topics:
Creary, Xavier
Aldridge, Timothy E.
The thioamide group, CSNMe2, when attached to a developing carbocationic center, can be a very effective carbocation stabilizing group.Stabilization occurs by either sulfur participation leading to the formation of cyclized ions or by extensive conjugative charge delocalization onto sulfur.
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