Bulletin of the Chemical Society of Japan p. 1456 - 1460 (1993)
Update date:2022-08-17
Topics:
Yamano, Toru
Tokuyama, Shinji
Aoki, Isao
Nishiguchi, Yumiko
Nakahama, Kazuo
Takanohashi, Kunio
The enzyme-catalyzed kinetic resolution of (+/-)-(3aα,4α,6aα)-4-acetoxy-1,3-dibenzyl-3a,4,6,6a-tetrahydro-1H-thieno<3,4-d>imidazol-2(3H)-one <(RS)-(3a)> was examined.Lipase B from Pseudomonas fragi and rabbit liver esterase gave (-)-<3aR(3aα,4α,6aα)>-1,3-dibenzyl-3a,4,6,6a-tetrahydro-4-hydroxy-1H-thieno<3,4-d>imidazol-2(3H)-one <(R)-(2)>, while Streptomyces rochei var. volubilis gave the alcohol (S)-(2), which is a key intermediate in the synthesis of d-biotin, with high enantioselectivity.
View More
Yangzhou Siyu Chemical Co.,Ltd.
Contact:+86-514-87325867 13358126196
Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
JIANGXI ZHANGFENG CHEMICAL CO., LTD.
Contact:+86-0799-3413066
Address:Xiyuan village, Xiabu Town, Xiangdong District
Xi'an Costrong Pharmaceutical Co., Ltd.
Contact:029- 68576496
Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Shanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Luoyang Aoda chemical Co.,Ltd.
Contact:+86-379-67518785 67516588
Address:MiaoWan industry district,YanShi City,Henan,China
Doi:10.1039/c3cc44124e
(2013)Doi:10.1007/s11030-019-10008-x
(2020)Doi:10.1016/j.tetasy.2006.09.009
(2006)Doi:10.1016/S0925-8388(03)00529-2
(2004)Doi:10.1039/c39720000452
(1972)Doi:10.1016/S0040-4039(00)89268-0
(1985)
