A NEW, STEREOCONTROLLED SYNTHESIS OF EQUATORIAL ALCOHOLS BY THE AMBIPHILIC REDUCTION OF CYCLOHEXANONES

DOI: 10.1016/S0040-4039(00)89268-0

Source and publish data:

Tetrahedron Letters p. 3853 - 3856 (1985)

Update date:2022-08-17

Topics:

Authors:

Maruoka, Keiji

Sakurai, Minoru

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)89268-0

Ambiphilic reduction of cyclohexanones with methylaluminium bis(2,6-di-tert-butyl-4-methylphenoxide) and tert-butylmagnesium chloride provides the corresponding equatorial alcohols with high stereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)89268-0

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