THE DIMESITYLBORON GROUP IN ORGANIC SYNTHESIS 7. A UNIQUE VARIANT OF THE BORON-WITTIG REACTION WHICH STEREOSELECTIVELY YIELDS 1,2-DIOLS.

DOI: 10.1016/S0040-4039(01)80861-3

Source and publish data:

Tetrahedron Letters p. 5093 - 5096 (1985)

Update date:2022-08-16

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Authors:

Pelter, Andrew

Buss, Dieter

Pitchford, Andrew

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Article abstract of DOI:10.1016/S0040-4039(01)80861-3

Low temperature oxidation of the intermediates in the Wittig reactions of aryl aldehydes with carbanions stabilised with an adjacent dimesitylboron group leads stereoselectively to erythro-1,2-diols.The mechanistic implications for the boron-Wittig reactions are discussed.

Full text of DOI:10.1016/S0040-4039(01)80861-3

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