Regioselective aromatic monobromination of alkyl phenyl ethers with NaClO2, NaBr, Mn(acac)3, and Montmorillonite K10 in dichloromethane

Article abstract of DOI:10.1080/00397919808005939

Regioselective and high-yielding nuclear monobromination of aromatic ethers can be accomplished with a combination of NaClO₂, NaBr, and Mn(acac)₃ catalyst in dilchloromethane under mild and neutral conditions with the aid of Montmorillonite K10.

Full text of DOI:10.1080/00397919808005939

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Synthetic Communications: An
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Regioselective Aromatic
Monobromination of Alkyl
Phenyl Ethers with NaClO2,
NaBr, Mn(acac) , and
3
Montmorillonite K10 in
Dichloromethane
a
a
Masao Hirano , Shigetaka Yakabe , Hiroyuki
a
a
Monobe & Takashi Morimoto
a
Department of Applied Chemistry, Faculty of
Technology , Tokyo University of Agriculture and
Technology , Koganei, Tokyo, 184, Japan
Published online: 02 Sep 2006.
To cite this article: Masao Hirano , Shigetaka Yakabe , Hiroyuki Monobe & Takashi
Morimoto (1998) Regioselective Aromatic Monobromination of Alkyl Phenyl Ethers
with NaClO , NaBr, Mn(acac) , and Montmorillonite K10 in Dichloromethane, Synthetic
2
3
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 28:4, 669-676, DOI: 10.1080/00397919808005939
To link to this article: http://dx.doi.org/10.1080/00397919808005939
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