Controlling Stereochemistry in Crotyl Additions To Aldehydes with Crotylmolybdenum Complexes

DOI: 10.1016/S0040-4039(00)99575-3

Source and publish data:

Tetrahedron Letters p. 1769 - 1772 (1989)

Update date:2022-08-11

Topics:

Authors:

Faller, J.W.

John, J.A.

Mazzieri, M.R.

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Article abstract of DOI:10.1016/S0040-4039(00)99575-3

Air stable (Cyclopentadienyl)Mo(NO)(Cl)(?-crotyl) complexes add to aldehydes in the presence of methanol to yield homoallylic alcohols with high regioselectivity and diastereoselectivity.Reaction of (-)-(S)-(Neomenthylcyclopentadienyl)Mo(NO)(Cl)(?-crotyl)

Full text of DOI:10.1016/S0040-4039(00)99575-3

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