Chemical and pharmaceutical bulletin p. 1215 - 1218 (2000)
Update date:2022-08-22
Topics:
Nagaoka
Endo
Numazawa
16Alpha-hydroxy-17-keto steroids, 1, 3, and 8, and their 17beta-hydroxy-16-keto isomers, 4, 5, and 9, were transformed into the corresponding 17beta-alkoxy-16-keto derivatives on treatment with trimethylsilyl iodide (TMSI) in the presence of alkyl alcohol in CHCl3 in poor to high yields.
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