Chemistry Letters p. 189 - 192 (1994)
Update date:2022-08-10
Topics:
Yamamoto, Keiji
Momose, Satoru
Funahashi, Masakazu
Ebata, Satoshi
Ohmura, Hideaki
et al.
The relevance of a new diphosphinite, which holds a natural bite angle around 120 deg in a catalyst complex, to the Rh(I)-catalyzed hydroformylation of certain olefins is examined, exhibiting a high turnover frequency (TOF) as compared with a typical 1,2-bis(diphenylphosphino)ethane with a bite angle around 85 deg.
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